张文雄  教授，博士生导师

2007.10, 北京大学化学学院副教授
2004.11-2007.9, 日本理化学研究所协力研究员
2004.1-2004.3, 日本北海道大学JST研究员
2002.10-2004.10, 北京大学化学学院博士后
2003.1, 获南开大学理学博士学位
1999.6, 获广西师范大学理学硕士学位
1996.7，获湖南师范大学化学教育学士学位

研究方向：稀土金属有机化学，活性金属有机化合物分离化学

电话：010-6275-8294
传真：010-6275-9728
电子信箱：wx_zhang@pku.edu.cn

研究领域与兴趣：

活性金属有机化合物的分离、单晶培养与结构表征；
稀土金属有机簇合物的设计、合成及反应性能研究

代表性论文

1. Wen-Xiong Zhang*, Dongzhen Li, Zitao Wang, and Zhenfeng Xi*. "Alkyl Aluminum Catalyzed Addition of Amines to Carbodiimides: A Highly Efficient Route to Substituted Guanidines". Organometallics 2009, 28, 882–887.

2. Wen-Xiong Zhang, and Zhenfeng Xi*. "1-Lithio-1,3-dienes as Useful Building Blocks in Organic Synthesis". Pure Appl. Chem. 2009, 81, 235–246. (Review)

3. Zhenfeng Xi*, and Wen-Xiong Zhang*. "Synthetic Methods for Multiply Substituted Butadiene-containing Building Blocks". Synlett 2008, 2557–2570.. (Account)

4. Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou*. "Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes". Angew. Chem. Int. Ed. 2008, 47, 9700-9703. (Highlighted by Synfacts and Riken Research)

5. Wen-Xiong Zhang, Masayoshi Nishiura, Tomohiro Mashiko, and Zhaomin Hou*. "Half-Sandwich o-N,N-Dimethylaminobenzyl Complexes over the Full Size Range of Group 3 and Lanthanide Metals. Synthesis, Structural Characterization, and Catalysis of Phosphine P–H Bond Addition to Carbodiimides". Chem. Eur. J. 2008, 14, 2167-2179. (VIP Highlight)

6. Wen-Xiong Zhang and Zhaomin Hou*. "Catalytic addition of alkyne C-H, amine N-H, and phosphine P-H bonds to carbodiimides: An efficient route to propiolamidines, guanidines, and phosphaguanidines". Org. Biomol. Chem. 2008, 6, 1720–1730. (Perspective Article, Inside Cover Picture)

7. Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou*. "Catalytic Addition of Amine N–H Bonds to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes: Efficient Synthesis of Substituted Guanidines through Amine Protonolysis of Rare Earth Metal Guanidinates". Chem. Eur. J. 2007, 13, 4307-4051.

8. Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou*. "Alkali-Metal-Catalyzed Addition of Primary and Secondary Phosphines to Carbodiimides. A General and Efficient Route to Substituted Phosphaguanidines". Chem. Commun. 2006, 3812-3814.

9. Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou*. "Catalytic Addition of Secondary Amines to Carbodiimides by a Half-Sandwich Yttrium Complex: An Efficient Route to N,N￠,N",N"-Tetrasubstituted Guanidines". Synlett 2006, 1213-1216. (Special Issue)

10. Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou*. "Catalytic Addition of Terminal Alkynes to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes". J. Am. Chem. Soc. 2005, 127, 16788-16789.

11. Zhenfeng Xi*, Wen-Xiong Zhang, Zhiyi Song, Weixin Zheng, Fanzhi Kong, and Tamotsu Takahashi*. "Preparation of Vinyl Allenes from 1-Lithio-1,3-Butadienyl Phosphine Oxides and Aldehydes by the Wittig-Horner Reaction". J. Org. Chem. 2005, 70, 8785-8789.

12. Zhenfeng Xi*, Wen-Xiong Zhang, Tamotsu Takahashi*. "Selective Preparation of 1,3-Butadienyl Phosphines, 1-Iodo- and 1,4-Diiodo- Butadienyl Phosphine Oxides via Zirconocene-Mediated Cross-coupling of Alkynylphosphines". Tetrahedron Lett. 2004, 45, 2427-2429.