林崇熙 博士，副教授
学士: 台湾大学
硕士: 美国 Clemson University
博士: 美国 University of Kentucky
博士后: 美国 SUNY Buffalo
北京大学化学学院
电话: 010-62753021, 62752753 传真: 010-62752632, 62754051
电子信箱: sslin@pku.edu.cn
研究领域和兴趣
| 核磁共振的应用 | 利用核磁共振的 2D、变温、多种核素检测技术研究化学反应的机理; 探讨简易核磁碳谱在各种溶液体系中定性与定量分析的应用; 以 NMR 检测手性化合物 e.e. 值与绝对构型的研究 (北大化学学院核磁学术组研究主题, 科技部十五科研攻关项目之一) |
| 有机合成 | 天然物木脂素、香料、手性衍生试剂的合成研究 |
| 氮叶立德化学 | 三苯基吡啶叶立德的化学研究以及官能基团转换反应的应用探讨 （国家自然科学基金科研项目） |
| 有机技术化学 | 微波、超声波、有机电化学在有机合成工作的应用探讨 |
教学:
核磁共振在化学中的应用 (2004-), 化学信息学 (1998-), 有机合成化学 (2000-2004), 立体化学 (1998)
Publications:
1. J. Org. Chem., 1996, 61, 9033-9034. John P. Richard, Shrong-Shi Lin, and Kathleen B. Williams. "Relative Reactivities of a Strongly Nucleophilic Alkene and Azide Ion in Aqueous Methanol"
2. J. Am. Chem. Soc., 1996, 118, 12603-12613. John P. Richard, Shrong-Shi Lin, Jeanne M. Buccigross, and Tina L. Amyes. "How Does Organic Structure Determine Organic Reactivity? Nucleophilic Substitution and Alkene-Forming Elimination Reactions of a-Carbonyl and a-Thiocarbonyl Substituted Benzyl Derivatives"
3.
4. Chin. Chem. Lett., 2000, 11, 11-14. Shrong-Shi LIN, Jun Hua YU, Jian Mei WANG, Bo YANG, Xiu Lin YE. "The Synthesis of 4-Arylcarbonyl-3-methoxycarbonyl- 2-phenylfurans by Friedel-Crafts Acylation Reactions"
5. Advances in Physical Organic Chemistry, 2000, 35, 67-115. J. P. Richard, T. L. Amyes, S.-S. Lin, A. C. O'Donoghue, M. M. Toteva, Y. Tsuji and K. B. Williams. "How Does Organic Structure Determine Organic Reactivity? Partitioning of Carbocations Between Addition of Nucleophiles and Deprotonation"
6. Heterocycles, 2001, 55 (2), 265-277. Shrong-Shi Lin, Xiaoping Nie, Junhua Yu, Xiulin Ye. "Regiosselective Friedel-Crafts Acylation with Unsymmetrically Substituted Furandicarboxylic Acid Anhydride and Furan Acid Chloride"
7. Chin. Chem. Lett., 2001, 12, 851-854. Xin ZHOU, Shrong-Shi LIN, Jin Fang YUAN*, Zhe Ming WANG. "Spectral and Mechanistic Studies of the Reactions of Substituted 1,5-Benzothiazepine with Dichloroacetyl Chloride and Triethylamine"
8. Chin. Chem. Lett., 2001, 12, 497-498. Xie, Gui Yang; Chen, Jia Hua; Lin, Shrong Shi; Jin, Sheng. "The synthesis of a novel phosphorus containing antigen.
9. Chin. Chem. Lett., 2002, 13, 597-600. Shrong-Shi LIN*, Jian Mei WANG, Xuan WANG, Cheng Yong LI. "Preparation and Reactions of Pyridinium Ylids via Decarboxylation of Pyridinium Betaines"
10. Chin. Chem. Lett., 2002, 13, 605-606. Shrong-Shi LIN*, Cheng Yong LI, Xuan WANG. "Efficient Synthesis of 2,6-Diphenyl-4-arylpyrylium Tetrafluoroborate"
11. 北京大学学报 (自然科学版) 2002, 38 (6), 739-743. 林崇熙*, 柳敬元, 王安. "酒石酸衍生物旋光与结构关系的探讨"
12. 分析化学, 2002, 30, 1279. 林崇熙*, 杨波. "正丁基锂的直接碳谱测试与简易浓度定量探讨"
13. 大学化学, 2002, 17, 39. 柳敬元, 林崇熙*. "对乙醇与浓碱水的分层现象的探讨"
14. 精细化工, 2002, 19, 356-357. 林崇熙*, 柳敬元. "2-十二烷基-4-甲基苯酚的合成"
15. Chin. Chem. Lett., 2002, 13, 826-829. Shrong-Shi LIN*, Bo YANG. "The Synthesis and Regioselective Hydrolysis of Dialkyl 2-Phenylfuran (and 2-Phenyltetrahydrofuran) -3,4-dicarboxylates"
16. Chem. J. on Internet, 2002, 4 (11), 51. Lin Shrong-Shi*, Liu Jingyuan. "The Application of 13C NMR on the Kinetic Study of the Reactions of Tartaric Acid Diester and Methylamine"
17. Chin. Chem. Lett., 2003, 14, 111-114. Shrong Shi LIN*, Jian Mei WANG, Cheng Yong LI. "The Reactivity of 2,4,6-Triphenylpyridinium Ylids"
18. Chin. Chem. Lett., 2003, 14, 883-884. Shrong Shi LIN*, Jing Yuan LIU, Jian Mei WANG. "The Synthesis of Cyclic Amino Acids"
19. Chin. Chem. Lett., 2003, 14, 907-910. Shrong-Shi LIN*, Xian Jing KONG, Jing Yuan LIU, Cheng Yong LI. "The Studies of the Reactions of 2, 4, 6-Triphenylpyrylium Tetrafluoroborate with Amino Acids"
20. 分析科学学报, 2003, 19 (4), 395-396 林崇熙*, 杨波, 潘金鹤. "简易核磁碳谱应用于有机锂试剂的结构信息探讨"
21. Helvetica Chimica Acta, 2005, 88 (1), 180-186. Jiaxi Xu, Tiezheng Wei, Shrong-Shi Lin, Qihan Zhang. "Rationale on the Abnormal Effect of Temperature on the Enantioselectivity in the Asymmetric Borane Reduction of Ketones Catalyzed by L-Prolinol"
22. 高等学校化学学报, 2007,(05), 913-917. 齐剑, 高秀香, 赵梅仙, 向俊峰, 林崇熙*, 徐怡庄*, 吴瑾光. "氧氟沙星的核磁共振波谱性质研究"
23. J. Phys. Chem. B, 2007, 111 (28), 8089-8095. Hang Xing, Shrong-Shi Lin, Peng Yan, Jin-Xin Xiao, Yong-Ming Chen. "NMR Studies on Selectivity of b-Cyclodextrin to Fluorinated/Hydrogenated Surfactant Mixtures"
24. Bioorganic and Medicinal Chemistry, 2007, 15, 265-272. Dekai Yuan, Meizi He, Ruifang Pang, Shrong-shi Lin, Zhengming Li and Ming Yang. "The design, synthesis and biological evaluation of novel substituted purines as HIV-1 Tat–TAR inhibitors "
25. 化学学报, 2008, 66 (11), 1382. 邢航, 林崇熙, 肖进新. "b-环糊精与十四烷基硫酸钠和全氟辛酸钠等莫尔体系的相互作用"
26. Langmuir, 2008, 24(19), 10654-10664. Xing, Hang; Lin, Shrong-Shi; Yan, Peng; Xiao, Jin-Xin. "Demicellization of a Mixture of Cationic-Anionic Hydrogenated/Fluorinated Surfactants through Selective Inclusion by a- and b-Cyclodextrin"
27. Macromolecules, 2008, 41 (14), 5433-5440. Huang, Xiaonan; Du, Fusheng; Liang, Dehai; Lin, Shrong-Shi; Li, Zichen. "Stereochemical Effect of Trans/Cis Isomers on the Aqueous Solution Properties of Acid-Labile Thermoresponsive Polymers"
28. Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 2008, 318(1-3), 199-205. Xing, Hang; Lin, Shrong-Shi; Lu, Run-Chao; Xiao, Jin-Xin. "NMR investigation on micellization of ammonium/tetraalkylammonium perfluorooctanoates"
29. Macromolecules, 2009, 42 (3), 783-790. Huang, Xiaonan; Du, Fusheng; Cheng, Jing; Dong, Yongquan; Liang, Dehai; Ji, Shouping; Lin, Shrong-Shi; Li, Zichen. "Acid-Sensitive Polymeric Micelles Based on Thermoresponsive Block Copolymers with Pendent Cyclic Orthoester Groups"
30. Environmental Science & Technology, 2009, 43 (6), 2041-2046. Zhao, Huazhang; Peng, Jianxiong; Lin, Shrongshi; Zhang, Yan. "Covalently bound organic silicate aluminum hybrid coagulants: preparation, characterization, and coagulation behavior"
31. J. Chem. Eng. Data, 2010, 55, 1940–1944. Hang Xing, Shrong-Shi Lin, and Jin-Xin Xiao. "A Study of the Behavior of a-Cyclodextrin with Single Solutions of Hydrogenated"
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